Werner Heisenberg

Werner Heisenberg (5 December 1901 – 1 February 1976) was a German theoretical physicist who made foundational contributions to quantum mechanics and is best known for asserting the uncertainty principle of quantum theory. In addition, he made important contributions to nuclear physics, quantum field theory, and particle physics.

Heisenberg, along with Max Born and Pascual Jordan, set forth the matrix formulation of quantum mechanics in 1925. Heisenberg was awarded the 1932 Nobel Prize in Physics for the creation of quantum mechanics, and its application especially to the discovery of the allotropic forms of hydrogen.

Following World War II, he was appointed director of the Kaiser Wilhelm Institute for Physics, which was soon thereafter renamed the Max Planck Institute for Physics. He was director of the institute until it was moved to Munich in 1958, when it was expanded and renamed the Max Planck Institute for Physics and Astrophysics.

From 1924 to 1927, Heisenberg was a Privatdozent at Göttingen. From 17 September 1924 to 1 May 1925, under an International Education BoardRockefeller Foundation fellowship, Heisenberg went to do research with Niels Bohr, director of the Institute of Theoretical Physics at the University of Copenhagen. He returned to Göttingen and with Max Born and Pascual Jordan, over a period of about six months, developed the matrix mechanicsformulation of quantum mechanics. On 1 May 1926, Heisenberg began his appointment as a university lecturer and assistant to Bohr in Copenhagen. It was in Copenhagen, in 1927, that Heisenberg developed his uncertainty principle, while working on the mathematical foundations of quantum mechanics. On 23 February, Heisenberg wrote a letter to fellow physicist Wolfgang Pauli, in which he first described his new principle. In his paper on the uncertainty principle, Heisenberg used the word "Ungenauigkeit" (imprecision).

Heisenberg was also president of the German Research Council, chairman of the Commission for Atomic Physics, chairman of the Nuclear Physics Working Group, and president of the Alexander von Humboldt Foundation.

In 1927, Heisenberg was appointed ordentlicher Professor (ordinarius professor) of theoretical physics and head of the department of physics at the Universität Leipzig; he gave his inaugural lecture on 1 February 1928. In his first paper published from Leipzig, Heisenberg used the Pauli exclusion principle to solve the mystery of ferromagnetism.

In Heisenberg's tenure at Leipzig, the quality of doctoral students, post-graduate and research associates who studied and worked with Heisenberg there is attested to by the acclaim later earned by these people; at various times, they included: Erich Bagge, Felix Bloch, Ugo Fano, Siegfried Flügge, William Vermillion Houston, Friedrich Hund, Robert S. Mulliken, Rudolf Peierls, George Placzek,Isidor Isaac Rabi, Fritz Sauter, John C. Slater, Edward Teller, John Hasbrouck van Vleck, Victor Frederick Weisskopf, Carl Friedrich von Weizsäcker, Gregor Wentzel and Clarence Zener.

In early 1929, Heisenberg and Pauli submitted the first of two papers laying the foundation for relativistic quantum field theory. Also in 1929, Heisenberg went on a lecture tour in the United States, Japan, China, and India.

Shortly after the discovery of the neutron by James Chadwick in 1932, Heisenberg submitted the first of three papers on his neutron-proton model of the nucleus. He was awarded the 1932Nobel Prize in Physics.

In 1928, the British mathematical physicist P. A. M. Dirac had derived the relativistic wave equation of quantum mechanics, which implied the existence of positive electrons, later to be namedpositrons. In 1932, from a cloud chamber photograph of cosmic rays, the American physicist Carl David Anderson identified a track as having been made by a positron. In mid-1933, Heisenberg presented his theory of the positron. His thinking on Dirac's theory and further development of the theory were set forth in two papers. The first, Bemerkungen zur Diracschen Theorie des Positrons (Remarks on Dirac's theory of the positron) was published in 1934, and the second, Folgerungen aus der Diracschen Theorie des Positrons (Consequences of Dirac's Theory of the Positron), was published in 1936. In these papers Heisenberg was the first to reinterpret the Dirac equation as a "classical" field equation for any point particle of spin ħ/2, itself subject to quantization conditions involving anti-commutators. Thus reinterpreting it as a (quantum) field equation accurately describing electrons, Heisenberg put matter on the same footing as electromagnetism: as being described by relativistic quantum field equations which allowed the possibility of particle creation and destruction.

In the early 1930s in Germany, the deutsche Physik movement was anti-Semitic and anti-theoretical physics, especially including quantum mechanics and the theory of relativity. As applied in the university environment, political factors took priority over the historically applied concept of scholarly ability, even though its two most prominent supporters were the Nobel Laureates in PhysicsPhilipp Lenard and Johannes Stark.

After Adolf Hitler came to power in 1933, Heisenberg was attacked in the press as a "White Jew" by elements of the deutsche Physik (German Physics) movement for his insistence on teaching about the roles of Jewish scientists. As a result, he came under investigation by the SS. This was over an attempt to appoint Heisenberg as successor to Arnold Sommerfeld at the University of Munich. The issue was resolved in 1938 by Heinrich Himmler, head of the SS. While Heisenberg was not chosen as Sommerfeld's successor, he was rehabilitated to the physics community during theThird Reich. Nevertheless, supporters of deutsche Physik launched vicious attacks against leading theoretical physicists, including Arnold Sommerfeld and Heisenberg. On 29 June 1936, a National Socialist Party newspaper published a column attacking Heisenberg. On 15 July 1937, he was attacked in a journal of the SS. This was the beginning of what is called the Heisenberg Affair.

In mid-1936, Heisenberg presented his theory of cosmic-ray showers in two papers. Four more papers appeared in the next two years.

Heisenberg’s paper establishing quantum mechanics has puzzled physicists and historians. His methods assume that the reader is familiar with Kramers-Heisenberg transition probability calculations. The main new idea, noncommuting matrices, is justified only by a rejection of unobservable quantities. It introduces the non-commutative multiplication of matrices by physical reasoning, based on the correspondence principle, despite the fact that Heisenberg was not then familiar with the mathematical theory of matrices. The path leading to these results has been reconstructed in MacKinnon, 1977, and the detailed calculations are worked out in Aitchison et al.

In June 1939, Heisenberg bought a summer home for his family in Urfeld, in southern Germany. He also traveled to the United States in June and July, visiting Samuel Abraham Goudsmit, at theUniversity of Michigan in Ann Arbor. However, Heisenberg refused an invitation to emigrate to the United States. He did not see Goudsmit again until six years later, when Goudsmit was the chief scientific advisor to the American Operation Alsos at the close of World War II. Ironically, Heisenberg was arrested under Operation Alsos and detained in England under Operation Epsilon.

In Copenhagen, Heisenberg and H. Kramers collaborated on a paper on dispersion, or the scattering from atoms of radiation whose wavelength is larger than the atoms. They showed that the successful formula Kramers had developed earlier could not be based on Bohr orbits, because the transition frequencies are based on level spacings which are not constant. The frequencies which occur in the Fourier transform of sharp classical orbits, by contrast, are equally spaced. But these results could be explained by a semi-classical Virtual State model: the incoming radiation excites the valence, or outer, electron to a virtual state from which it decays. In a subsequent paper Heisenberg showed that this virtual oscillator model could also explain the polarization of fluorescent radiation.

These two successes, and the continuing failure of the Bohr-Sommerfeld model to explain the outstanding problem of the anomalous Zeeman effect, led Heisenberg to use the virtual oscillator model to try to calculate spectral frequencies. The method proved too difficult to immediately apply to realistic problems, so Heisenberg turned to a simpler example, the anharmonic oscillator.

The dipole oscillator consists of a simple harmonic oscillator, which is thought of as a charged particle on a spring, perturbed by an external force, like an external charge. The motion of the oscillating charge can be expressed as a Fourier series in the frequency of the oscillator. Heisenberg solved for the quantum behavior by two different methods. First, he treated the system with the virtual oscillator method, calculating the transitions between the levels that would be produced by the external source.

He then solved the same problem by treating the anharmonic potential term as a perturbation to the harmonic oscillator and using the perturbation methods that he and Born had developed. Both methods led to the same results for the first and the very complicated second order correction terms. This suggested that behind the very complicated calculations lay a consistent scheme.

So Heisenberg set out to formulate these results without any explicit dependence on the virtual oscillator model. To do this, he replaced the Fourier expansions for the spatial coordinates by matrices, matrices which corresponded to the transition coefficients in the virtual oscillator method. He justified this replacement by an appeal to Bohr’s correspondence principle and the Pauli doctrine that quantum mechanics must be limited to observables.

On 9 July, Heisenberg gave Born this paper to review and submit for publication. When Born read the paper, he recognized the formulation as one which could be transcribed and extended to the systematic language of matrices, which he had learned from his study under Jakob Rosanes at Breslau University. Born, with the help of his assistant and former student Pascual Jordan, began immediately to make the transcription and extension, and they submitted their results for publication; the paper was received for publication just 60 days after Heisenberg's paper. A follow-on paper was submitted for publication before the end of the year by all three authors. (A brief review of Born's role in the development of the matrix mechanics formulation of quantum mechanics along with a discussion of the key formula involving the non-commutivity of the probability amplitudes can be found in an article by Jeremy Bernstein, Max Born and the Quantum Theory. A detailed historical and technical account can be found in Mehra and Rechenberg's book The Historical Development of Quantum Theory. Volume 3. The Formulation of Matrix Mechanics and Its Modifications 1925–1926.)

Up until this time, matrices were seldom used by physicists; they were considered to belong to the realm of pure mathematics. Gustav Mie had used them in a paper on electrodynamics in 1912 and Born had used them in his work on the lattices theory of crystals in 1921. While matrices were used in these cases, the algebra of matrices with their multiplication did not enter the picture as they did in the matrix formulation of quantum mechanics.

Born had learned matrix algebra from Rosanes, as already noted, but Born had also learned Hilbert's theory of integral equations and quadratic forms for an infinite number of variables as was apparent from a citation by Born of Hilbert's work Grundzüge einer allgemeinen Theorie der Linearen Integralgleichungen published in 1912. Jordan, too was well equipped for the task. For a number of years, he had been an assistant to Richard Courant at Göttingen in the preparation of Courant and David Hilbert's book Methoden der mathematischen Physik I, which was published in 1924. This book, fortuitously, contained a great many of the mathematical tools necessary for the continued development of quantum mechanics. In 1926, John von Neumann became assistant to David Hilbert, and he coined the term Hilbert space to describe the algebra and analysis which were used in the development of quantum mechanics.

In 1928, Albert Einstein nominated Heisenberg, Born, and Jordan for the Nobel Prize in Physics, but it was not to be. The announcement of the Nobel Prize in Physics for 1932 was delayed until November 1933. It was at that time that it was announced Heisenberg had won the Prize for 1932 "for the creation of quantum mechanics, the application of which has, inter alia, led to the discovery of the allotropic forms of hydrogen" and Erwin Schrödinger and Paul Adrien Maurice Dirac shared the 1933 Prize "for the discovery of new productive forms of atomic theory". One can rightly ask why Born was not awarded the Prize in 1932 along with Heisenberg – Bernstein gives some speculations on this matter. One of them is related to Jordan joining the Nazi Party on 1 May 1933 and becoming a Storm Trooper. Hence, Jordan's Party affiliations and Jordan's links to Born may have affected Born's chance at the Prize at that time. Bernstein also notes that when Born won the Prize in 1954, Jordan was still alive, and the Prize was awarded for the statistical interpretation of quantum mechanics, attributable alone to Born.

In 1939, shortly after the discovery of nuclear fission, the German nuclear energy project, also known as the Uranverein (Uranium Club), was begun. Heisenberg was one of the principal scientists leading research and development in the project.^{[citation needed]}

Heisenberg's reaction to Born for Heisenberg receiving the Prize for 1932 and to Born for Born receiving the Prize in 1954 are also instructive in evaluating whether Born should have shared the Prize with Heisenberg. On 25 November 1933, Born received a letter from Heisenberg in which he said he had been delayed in writing due to a "bad conscience" that he alone had received the Prize "for work done in Göttingen in collaboration – you, Jordan and I." Heisenberg went on to say that Born and Jordan's contribution to quantum mechanics cannot be changed by "a wrong decision from the outside." In 1954, Heisenberg wrote an article honoring Max Planck for his insight in 1900. In the article, Heisenberg credited Born and Jordan for the final mathematical formulation of matrix mechanics and Heisenberg went on to stress how great their contributions were to quantum mechanics, which were not "adequately acknowledged in the public eye."

From 15 to 22 September 1941, Heisenberg traveled to German-occupied Copenhagen to lecture and discuss nuclear research and theoretical physics with Niels Bohr. The meeting, and specifically what it might reveal about Heisenberg's intentions concerning developing nuclear weapons for the Nazi regime, is the subject of the award winning Michael Frayn play titled Copenhagen. Documents relating to the Bohr-Heisenberg meeting were released in 2002 by the Niels Bohr Archive and by the Heisenberg family.

On 26 February 1942, Heisenberg presented a lecture to Reich officials on energy acquisition from nuclear fission, after the Army withdrew most of its funding. The Uranium Club was transferred to the Reich Research Council (RFR) in July 1942. On 4 June 1942, Heisenberg was summoned to report to Albert Speer, Germany's Minister of Armaments, on the prospects for converting the Uranium Club's research toward developing nuclear weapons. During the meeting, Heisenberg told Speer that a bomb could not be built before 1945, and would require significant monetary and manpower resources. Five days later, on 9 June 1942, Adolf Hitler issued a decree for the reorganization of the RFR as a separate legal entity under the Reich Ministry for Armament and Ammunition; the decree appointed Reich Marshall Göring as the president.

In September 1942, Heisenberg submitted his first paper of a three-part series on the scattering matrix, or S-matrix, in elementary particle physics. The first two papers were published in 1943^[and the third in 1944. The S-matrix described only observables, i.e., the states of incident particles in a collision process, the states of those emerging from the collision, and stable bound states; there would be no reference to the intervening states. This was the same precedent as he followed in 1925 in what turned out to be the foundation of the matrix formulation of quantum mechanics through only the use of observables.

In February 1943, Heisenberg was appointed to the Chair for Theoretical Physics at the Friedrich-Wilhelms-Universität (today, the Humboldt-Universität zu Berlin). In April, his election to the Preußische Akademie der Wissenschaften (Prussian Academy of Sciences) was approved. That same month, he moved his family to their retreat in Urfeld as Allied bombing increased in Berlin. In the summer, he dispatched the first of his staff at the Kaiser-Wilhelm Institut für Physik to Hechingen and its neighboring town of Haigerloch, on the edge of the Black Forest, for the same reasons. From 18–26 October, he traveled to German-occupied Netherlands. In December 1943, Heisenberg visited German-occupied Poland.

From 24 January to 4 February 1944, Heisenberg traveled to occupied Copenhagen, after the German Army confiscated Bohr's Institute of Theoretical Physics. He made a short return trip in April. In December, Heisenberg lectured in neutral Switzerland.

In January 1945, Heisenberg vacated the Kaiser-Wilhelm Institut für Physik with about all of his staff for the facilities in the Black Forest.

Niels Bohr

Niels Henrik David Bohr ( 7 October 1885 – 18 November 1962) was a Danish physicist who made fundamental contributions to understanding atomic structure and quantum mechanics, for which he received the Nobel Prize in Physics in 1922. Bohr mentored and collaborated with many of the top physicists of the century at his institute in Copenhagen. He was part of a team of physicists working on the Manhattan Project. Bohr married Margrethe Nørlund in 1912, and one of their sons, Aage Bohr, grew up to be an important physicist who in 1975 also received the Nobel Prize. Bohr has been described as one of the most influential scientists of the 20th century.In 1922, Bohr was awarded the Nobel Prize in physics "for his services in the investigation of the structure of atoms and of the radiation emanating from them." The award recognized his early leading work in the emerging field of Quantum Mechanics.

While at Manchester University, Bohr had adapted Rutherford's nuclear structure to Max Planck's quantum theory and so obtained a model of atomic structure which, with later improvements – mainly as a result of Heisenberg's concepts – remains valid to this day. Bohr published his model of atomic structure in 1913. Here he introduced the theory of electrons traveling in orbits around the atom'snucleus, the chemical properties of each element being largely determined by the number of electrons in the outer orbits of its atoms. Bohr also introduced the idea that an electron could drop from a higher-energy orbit to a lower one, in the process emitting a photon (light quantum) of discrete energy. This became a basis for quantum theory.

Among the international community of nuclear physicists, Bohr came to play the role of convener of discussion groups and lectures, as well as being a mentor and an advisor. With the assistance of the Danish government and the Carlsberg Foundation, he succeeded in founding the Institute of Theoretical Physics in 1921, of which he became director. Bohr's institute served as a focal point for researchers into Quantum Mechanics and related subjects in the 1920s and '30s, when most of the world's best known theoretical physicists spent some time in his company. Bohr became widely appreciated as their congenial host and eminent colleague, both at the Institute and at the Foundation's mansion in Carlsberg, where he and his family resided after 1932.

Bohr also conceived the principle of complementarity: that items could be separately analyzed as having several contradictory properties. For example, physicists currently conclude that light behaves either as a wave or a stream of particles depending on the experimental framework – two apparently mutually exclusive properties – on the basis of this principle. Bohr found philosophical applications for this daring principle.^[specify] Albert Einstein much preferred the determinism of classical physics over the probabilistic new quantum physics (to which among many others Einstein himself had 'unwittingly' contributed). Philosophical issues that arose from the novel aspects of Quantum Mechanics became widely celebrated subjects of discussion. Einstein and Bohr had good-natured arguments over such issues throughout their lives. See article Bohr–Einstein debates.

Werner Heisenberg worked as an assistant to Bohr and university lecturer in Copenhagen from 1926 to 1927. It was in Copenhagen, in 1927, that Heisenberg developed his uncertainty principle, while working on the mathematical foundations of quantum mechanics. Heisenberg later became head of the German nuclear energy project. In April 1940, early in World War II, Germany invaded and occupied Denmark. In September 1941, Bohr was visited by Heisenberg in Copenhagen.

Michael Faraday

Michael Faraday, FRS (22 September 1791 – 25 August 1867) was an English chemist and physicist (or natural philosopher, in the terminology of the time) who contributed to the fields of electromagnetism and electrochemistry.

Faraday studied the magnetic field around a conductor carrying a DC electric current. While conducting these studies, Faraday established the basis for the electromagnetic field concept in physics, subsequently enlarged upon by James Maxwell. He similarly discovered electromagnetic induction, diamagnetism, and laws of electrolysis. He established that magnetism could affect rays of light and that there was an underlying relationship between the two phenomena. His inventions of electromagnetic rotary devices formed the foundation of electric motor technology, and it was largely due to his efforts that electricity became viable for use in technology.

As a chemist, Faraday discovered benzene, investigated the clathrate hydrate of chlorine, invented an early form of the Bunsen burner and the system of oxidation numbers, and popularised terminology such as anode, cathode, electrode, and ion.

Although Faraday received little formal education and knew little of higher mathematics, such as calculus, he was one of the most influential scientists in history. Historians of science refer to him as the best experimentalist in the history of science. The SI unit of capacitance, thefarad, is named after him, as is the Faraday constant, the charge on a mole of electrons (about 96,485 coulombs). Faraday's law of induction states that magnetic flux changing in time creates a proportional electromotive force.

Faraday was the first and foremost Fullerian Professor of Chemistry at the Royal Institution of Great Britain, a life-time position.

Albert Einstein kept a photograph of Faraday on his study wall alongside pictures of Isaac Newton and James Clerk Maxwell.

Faraday's earliest chemical work was as an assistant to Humphry Davy. Faraday specifically studied chlorine, discovering two new chlorides of carbon. He also made the first rough experiments on the diffusion of gases, a phenomenon first pointed out by John Dalton, the physical importance of which was more fully brought to light byThomas Graham and Joseph Loschmidt. He succeeded in liquefying several gases; he investigated the alloys of steel, and produced several new kinds of glass intended for optical purposes. A specimen of one of these heavy glasses afterwards became historically important as the substance in which Faraday detected the rotation of the plane of polarisation of light when the glass was placed in a magnetic field, and also as the substance that was first repelled by the poles of the magnet. He also endeavoured, with some success, to make the general methods of chemistry, as distinguished from its results, the subject of special study and of popular exposition.

Faraday was highly religious; he was a member of the Sandemanian Church, a Christian sect founded in 1730 that demanded total faith and commitment. Biographers have noted that "a strong sense of the unity of God and nature pervaded Faraday's life and work."

He invented an early form of what was to become the Bunsen burner, which is used almost universally in science laboratories as a convenient source of heat. Faraday worked extensively in the field of chemistry, discovering chemical substances such as benzene (which he called bicarburet of hydrogen), and liquefying gases such as chlorine. Liquification of gases helped establish that gases are simply the vapours of liquids possessing a very low boiling-point, and gave a more solid basis to conceptions of molecular aggregation. In 1820 Faraday reported on the first syntheses of compounds made from carbon and chlorine, C₂Cl₆ and C₂Cl₄, and published his results the following year. Faraday also determined the composition of the chlorine clathrate hydrate, which had been discovered by Humphry Davy in 1810.

Faraday also discovered the laws of electrolysis and popularised terminology such as anode, cathode, electrode, and ion, terms largely created by William Whewell.

Faraday is best known for his work with electricity and magnetism. His first recorded experiment was the construction of a voltaic pile with seven halfpence pieces, stacked together with seven disks of sheet zinc, and six pieces of paper moistened with salt water. With this pile he decomposed sulphate of magnesia (first letter to Abbott, 12 July 1812).In 1821, soon after the Danish physicist and chemist, Hans Christian Ørsted discovered the phenomenon ofelectromagnetism, Davy and British scientist William Hyde Wollaston tried but failed to design an electric motor. Faraday, having discussed the problem with the two men, went on to build two devices to produce what he called electromagnetic rotation: a continuous circular motion from the circular magnetic force around a wire and a wire extending into a pool of mercury with a magnet placed inside that would rotate around the magnet if supplied with current from a chemical battery. The latter device is known as a homopolar motor. These experiments and inventions form the foundation of modern electromagnetic technology. In his excitement, Faraday published results without acknowledging his work with either Wollaston or Davy. The resulting controversy within the Royal Society strained his mentor relationship with Davy and may well have contributed to Faraday’s assignment to other activities, thereby removing him from electromagnetic research for several years.Faraday's breakthrough came when he wrapped two insulated coils of wire around an iron^{[verification needed]} ring, and found that, upon passing a current through one coil, a momentary current was induced in the other coil.This phenomenon is known as mutual induction. The iron ring-coil apparatus is still on display at the Royal Institution. In subsequent experiments, he found that, if he moved a magnet through a loop of wire, an electric current flowed in the wire. The current also flowed if the loop was moved over a stationary magnet. His demonstrations established that a changing magnetic field produces an electric field. This relation was modelled mathematically by James Clerk Maxwell as Faraday's law, which subsequently became one of the four Maxwell equations. These in turn have evolved into the generalisation known today as field theory.

From his initial electromagnetic discovery in 1821, Faraday continued his laboratory work exploring properties of materials and developing the requisite experience. In 1824, Faraday briefly set up a circuit to study whether a magnetic field could regulate the flow of a current in an adjacent wire, but could find no such relationship. This lab followed similar work with light and magnets three years earlier with identical results. During the next seven years, Faraday spent much of his time perfecting his recipe for optical quality (heavy) glass, boro-silicate of lead, which he used in his future studies connecting light with magnetism. In his spare time from this optics work, Faraday continued publishing his experimental work (some of which related to EM) and conducted foreign correspondence with scientists (also working on EM) he previously met on his journeys about Europe with Davy. Two years after the death of Davy, in 1831, he began his great series of experiments in which he discovered electromagnetic induction. Joseph Henry likely discovered self-induction a few months earlier and both may have been anticipated by the work of Francesco Zantedeschi in Italy in 1829 and 1830.

Faraday later used the principle to construct the electric dynamo, the ancestor of modern power generators.

In 1839, he completed a series of experiments aimed at investigating the fundamental nature of electricity. Faraday used "static", batteries, and "animal electricity" to produce the phenomena of electrostatic attraction, electrolysis, magnetism, etc. He concluded that, contrary to scientific opinion of the time, the divisions between the various "kinds" of electricity were illusory. Faraday instead proposed that only a single "electricity" exists, and the changing values of quantity and intensity (current and voltage) would produce different groups of phenomena.

Near the end of his career, Faraday proposed that electromagnetic forces extended into the empty space around the conductor. This idea was rejected by his fellow scientists, and Faraday did not live to see this idea eventually accepted. Faraday's concept of lines of flux emanating from charged bodies and magnets provided a way to visualise electric and magnetic fields. That mental model was crucial to the successful development of electromechanical devices that dominated engineering and industry for the remainder of the 19th century.

Faraday was the first to report what later came to be called metallic nanoparticles. In 1847 he discovered that the optical properties of gold colloids differed from those of the corresponding bulk metal. This was probably the first reported observation of the effects of quantum size, and might be considered to be the birth of nanoscience.

Max Planck

Max Karl Ernst Ludwig Planck, ForMemRS, (April 23, 1858 – October 4, 1947) was a German physicist who is regarded as the founder of thequantum theory, for which he received the Nobel Prize in Physics in 1918.In Berlin, Planck joined the local Physical Society. He later wrote about this time: "In those days I was essentially the only theoretical physicist there, whence things were not so easy for me, because I started mentioning entropy, but this was not quite fashionable, since it was regarded as a mathematical spook". Thanks to his initiative, the various local Physical Societies of Germany merged in 1898 to form the German Physical Society (Deutsche Physikalische Gesellschaft, DPG); from 1905 to 1909 Planck was the president.

Planck started a six-semester course of lectures on theoretical physics, "dry, somewhat impersonal" according to Lise Meitner, "using no notes, never making mistakes, never faltering; the best lecturer I ever heard" according to an English participant, James R. Partington, who continues: "There were always many standing around the room. As the lecture-room was well heated and rather close, some of the listeners would from time to time drop to the floor, but this did not disturb the lecture". Planck did not establish an actual "school"; the number of his graduate students was only about 20, among them:

1897 Max Abraham (1875–1922)

1904 Moritz Schlick (1882–1936)

1906 Walther Meißner (1882–1974)

1906 Max von Laue (1879–1960)

1907 Fritz Reiche (1883–1960)

1912 Walter Schottky (1886–1976)

1914 Walther Bothe (1891–1957)

At the onset of the First World War Planck endorsed the general excitement of the public, writing that, "Besides much that is horrible, there is also much that is unexpectedly great and beautiful: the smooth solution of the most difficult domestic political problems by the unification of all parties (and) ... the extolling of everything good and noble."

Nonetheless, Planck refrained from the extremes of nationalism. In 1915, at a time when Italy was about to join the Allied Powers, he voted successfully for a scientific paper from Italy, which received a prize from the Prussian Academy of Sciences, where Planck was one of four permanent presidents.

Planck also signed the infamous "Manifesto of the 93 intellectuals", a pamphlet of polemic war propaganda (while Einstein retained a strictly pacifistic attitude which almost led to his imprisonment, being spared by his Swiss citizenship). But in 1915 Planck, after several meetings with Dutch physicist Lorentz, he revoked parts of the Manifesto. Then in 1916 he signed a declaration against German annexationism.

Mary Leakey

Mary Leakey (6 February 1913 – 9 December 1996) was a British archaeologist and anthropologist, who discovered the first skull of a fossil ape onRusinga Island and also a noted robust Australopithecine called Zinjanthropus at Olduvai. For much of her career she worked together with her husband, Louis Leakey, in Olduvai Gorge, uncovering the tools and fossils of ancient hominines. She developed a system for classifying the stone tools found at Olduvai. She also discovered the Laetoli footprints. In 1960 she became director of excavation at Olduvai and subsequently took it over, building her own staff. After the death of her husband she became a leading palaeoanthropologist, helping to establish the Leakey tradition by training her son, Richard, in the field.

Mary Leakey was born Mary Douglas Nicol on 6 February 1913 in London, England to Erskine Edward Nicol and Cecilia Marion (Frere) Nicol. Since Erskine worked as a painter, specializing in watercolor landscapes, the Nicol family would move from place to place, visiting numerous locations in France, Italy, and Egypt where Erskine painted scenes to be sold in England. Erskine Nicol developed an amateur enthusiasm for Egyptologyduring his travels. Mary Leakey was a direct descendant of antiquarian, John Frere, and cousin to archaeologist, Sheppard Frere, on her mother's side. The Frere family had been active abolitionists in the British colonial empire during the nineteenth century and established several communities for freed slaves. Three of these communities remained in existence as of Mrs. Leakey's 1984 autobiography: Freretown, Kenya,Freretown, South Africa, and Freretown, India. She also was a distant relative of baronet Henry Bartle Frere.

The Nicols spent much of their time in southern France. Mary became fluent in French. She identified more with the adventurous spirit of her father, going for long walks and explorations with him and having long talks. She disliked her governess and had less sympathy for her mother.

In 1925, when Mary was 12, the Nicols stayed at Les Eyzies at a time when Elie Peyrony was excavating one of the caves there. Peyrony did not understand the significance of much of what he found, and was not excavating scientifically during that early stage of archaeology. Mary received permission to go through his dump. It was there that her interest in prehistory was sparked. She started a collection of points, scrapers, and blades from the dump and developed her first system of classification.

That winter, the family moved to Cabrerets, a village of Dordogne, France. There she met Abbé Lemozi, the village priest, who befriended her and became her mentor for a time. The two toured Pech Merle cave to view the prehistoric paintings of bison and horses.

Mary Curie

Marie Skłodowska Curie (7 November 1867 – 4 July 1934) was a Polish–French physicist–chemist famous for her pioneering research onradioactivity. She was the first person honored with two Nobel Prizes—in physics and chemistry. She was the first female professor at theUniversity of Paris. She was the first woman to be entombed on her own merits (in 1995) in the Paris Panthéon.^{[citation needed]}

She was born Maria Salomea Skłodowska in Warsaw, in Russian Poland, and lived there to the age of 24. In 1891 she followed her older sister Bronisława to study in Paris, where she earned her higher degrees and conducted her subsequent scientific work. She shared her Nobel Prize in Physics (1903) with her husband Pierre Curie (and with Henri Becquerel). Her daughter Irène Joliot-Curie and son-in-law, Frédéric Joliot-Curie, would similarly share a Nobel Prize. She was the sole winner of the 1911 Nobel Prize in Chemistry. Curie was the first woman to win a Nobel Prize, and is the only woman to win in two fields, and the only person to win in multiple sciences.

Her achievements include a theory of radioactivity (a term that she coined), techniques for isolating radioactive isotopes, and the discovery of two elements, polonium and radium. Under her direction, the world's first studies were conducted into the treatment of neoplasms, using radioactive isotopes. She founded the Curie Institutes: the Curie Institute (Paris) and the Curie Institute (Warsaw).

In 1903 the Royal Swedish Academy of Sciences awarded Pierre Curie, Marie Curie and Henri Becquerel the Nobel Prize in Physics, "in recognition of the extraordinary services they have rendered by their joint researches on the radiation phenomena discovered by Professor Henri Becquerel."

While an actively loyal French citizen, Skłodowska–Curie (as she styled herself) never lost her sense of Polish identity. She taught her daughters the Polish language and took them on visits to Poland. She named the first chemical element that she discovered "polonium" (1898) for her native country. During World War I she became a member of the Committee for a Free Poland (Komitet Wolnej Polski). In 1932 she founded a Radium Institute (now the Maria Skłodowska–Curie Institute of Oncology) in her home town, Warsaw, headed by her physician-sister Bronisława.

Skłodowska–Curie and her husband were unable to go to Stockholm to receive the prize in person, but they shared its financial proceeds with needy acquaintances, including students.

On receiving the Nobel Prize, Marie and Pierre Curie suddenly became very famous. The Sorbonne gave Pierre a professorship and permitted him to establish his own laboratory, in which Skłodowska–Curie became the director of research.

In 1897 and 1904, respectively, Skłodowska–Curie gave birth to their daughters, Irène and Eve Curie. She later hired Polish governessesto teach her daughters her native language, and sent or took them on visits to Poland.

Skłodowska–Curie was the first woman to be awarded a Nobel Prize. Eight years later, she would receive the 1911 Nobel Prize in Chemistry, "in recognition of her services to the advancement of chemistry by the discovery of the elements radium and polonium, by the isolation of radium and the study of the nature and compounds of this remarkable element."

A month after accepting her 1911 Nobel Prize, she was hospitalized with depression and a kidney ailment.Skłodowska–Curie was the first person to win or share two Nobel Prizes. She is one of only two people who have been awarded a Nobel Prize in two different fields, the other person being Linus Pauling (for chemistry and for peace). Nevertheless, in 1911 the French Academy of Sciences refused to abandon its prejudice against women, and she failed by two votes to be elected a member. Elected instead was Édouard Branly, an inventor who had helped Guglielmo Marconi develop the wireless telegraph. It would be a doctoral student of Skłodowska–Curie, Marguerite Perey, who would become the first woman elected to membership in the Academy – over half a century later, in 1962.

Louis de Broglie

Louis-Victor-Pierre-Raymond, 7th duc de Broglie, FRS ( 15 August 1892 – Louveciennes, France, 19 March 1987) was a French physicist and a Nobel laureate in the year 1929. He was the sixteenth member elected to occupy seat 1 of the Académie française in 1944, and served as Perpetual Secretary of the Académie des sciences, France.

Louis de Broglie was born to a noble family in Dieppe, Seine-Maritime, younger son of Victor, 5th duc de Broglie. He became the 7th duc de Broglieupon the death without heir in 1960 of his older brother, Maurice, 6th duc de Broglie, also a physicist. He did not marry. When he died inLouveciennes, he was succeeded as duke by a distant cousin, Victor-François, 8th duc de Broglie.

De Broglie had originally intended a career in humanities, and received his first degree in history. Afterwards, though, he turned his attention toward mathematics and physics and received a degree in physics. With the outbreak of the First World War in 1914, he offered his services to the army in the development of radio communications.

His 1924 , Recherches sur la théorie des quanta (Research on the Theory of the Quanta), introduced his theory of electron waves. This included thewave-particle duality theory of matter, based on the work of Max Planck and Albert Einstein on light. The thesis examiners, unsure of the material, passed his thesis to Einstein for evaluation who endorsed his wave-particle duality proposal wholeheartedly; de Broglie was awarded his doctorate. This research culminated in the de Broglie hypothesis stating that any moving particle or object had an associated wave. De Broglie thus created a new field in physics, the mécanique ondulatoire, or wave mechanics, uniting the physics of energy (wave) and matter (particle). For this he won the Nobel Prize in Physics in 1929.

In his later career, de Broglie worked to develop a causal explanation of wave mechanics, in opposition to the wholly probabilistic models which dominate quantum mechanical theory; it was refined byDavid Bohm in the 1950s.

In addition to strictly scientific work, de Broglie thought and wrote about the philosophy of science, including the value of modern scientific discoveries.

De Broglie became a member of the Académie des sciences in 1933, and was the academy's perpetual secretary from 1942. On 12 October 1944, he was elected to the Académie française, replacing mathematician Émile Picard. Because of the deaths and imprisonments of Académie members during the occupation and other effects of the war, the Académie was unable to meet the quorum of twenty members for his election; due to the exceptional circumstances, however, his unanimous election by the seventeen members present was accepted. In an event unique in the history of the Académie, he was received as a member by his own brother Maurice, who had been elected in 1934. UNESCO awarded him the first Kalinga Prize in 1952 for his work in popularizing scientific knowledge, and he was elected a Foreign Member of the Royal Society on 23 April 1953. In 1961 he received the title of Knight of the Grand Cross in the Légion d'honneur. De Broglie was awarded a post as counselor to the French High Commission of Atomic Energy in 1945 for his efforts to bring industry and science closer together. He established a center for applied mechanics at the Henri Poincaré Institute, where research into optics, cybernetics, and atomic energy were carried out. He inspired the formation of the International Academy of Quantum Molecular Science and was an early member.